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Question & Answer: When one mole of naphthalene is dissolved in 1000. g of benzene, the freezing point changes…..

When one mole of naphthalene is dissolved in 1000. g of benzene, the freezing point changes from 5.51 °C to 0.41 °C. When 20. g of an unknown organic compound is dissolved in 500. g of benzene the freezing point of this solution is 5.00 °C. What is the molar mass of the unknown organic compound? 40. g/mol O 100. g/mol O 128 g/mol O 200. g/mol O 400. g/mol

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When one mole of naphthalene is dissolved in 1000. g of benzene, the freezing point changes from 5.51 degree C to 0.41 degree C. When 20. g of an unknown organic compound is dissolved in 500. g of benzene, the freezing point of this solution is 5.00 degree C. What is the molar mass of the unknown organic compound? 40. g/mol 100. g/mol 128 g/mol 200. g/mol 400. g/mol

Expert Answer

We know depression in freezing point is given by

Delta T_{f}=K_{f}*m

where Delta T_{f} is depression in freezing point

Kf is ebuilliscopic constant

and m is molality of substance

Given intially when one mole of napthalene is dissolved in 1 kg of benzene solution

so Delta T_{f}=5.51-0.41=5.1^{o}C

m=1/1=1 m

therefore kf=5.1

In next case let molecualr weight of organic compound be M

So moles of it=20/M

now mass of benzene=0.5 kg

molality=m=20/M*0.5=40/M

now Kf=5.1 and Delta T_{f}=5.51-5=0.51

so 0.51=40/M*5.1

thus M=400 g

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