Question & Answer: When a 28.0 mL sample of a 0.339 M aqueous nitrous acid solution is titrated with…..

When a 28.0 mL sample of a 0.339 M aqueous nitrous acid solution is titrated with a 0.423 M aqueouspotassium hydroxide solution, what is the pH at the midpoint in the titration?

Expert Answer

Answer

HNO2 , Ka = 5.6×10–4

at mid point moles of acid = moles of salt formed

so pH =pKa

pKa = -log Ka

pKa = -log ( 5.6×10–4)

pKa = 3.25

pH = 3.25

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