Question & Answer: Equation for determining the radius of a simple cubic unit ceil is r = l/2 Equation for…..

(1) Equation for determining the radius of a simple cubic unit cell is r =- (2) Equation for detemining the radius of a face-centered cubic unit cell is (3) Equaton for detemining the radius of a body-centered cubic unit cell is An unknown element crystallizes in a body-centered cubiclatice structure. The edge of the unit cel is 2.86A. The density of the unknown crystal is 7.92 gmL Which of the following expressions can be used to detemine the atomic mass of he unknown element? 6.022 x 1023 atoms mol A. (2.86 x 10 cmx 7.92 2 atoms g 6.022x 10 atoms cm B. 2.86 x 10°cm x 7.92 x x2 atoms mol c. (2.86x 10* c)x 792 * 6. mo 022 x 10 atoms 2 atoms 1 cm6.022 x 10 atoms 792g x-1 D. (2.86 x 10 an), x mol 2 atoms E. None of the above

Equation for determining the radius of a simple cubic unit ceil is r = l/2 Equation for determining the radius of a face-centered cubic unit cell is r = l Squareroot 2/4 Equation for determining the radius of a body-centered cubic unit cell is r = l Squareroot 3/4 An unknown element crystallizes in a body-centered cubic lattice structure. The edge of the unit cell is 2.86 A. The density of the unknown crystal is 7.92 g/mL. Which of the following expressions can be used to determine the atomic mass of the unknown element? A. (2.86 times 10^-3 cm)^3 times 7.92 g/cm^3 times 6.022 times 10^23 atoms/mol times 1/2 atoms B. 2.86 times 10^-3 cm times 7.92 g/cm^3 times 6.022 times 10^23 atoms/mol times 2 atoms C. (2.86 times 10^-3 cm)^3 times 7.92 g/cm^3 times 1 mol/6.022 times 10^23 atoms times 1/2 atoms D. (2.86 times 10^-3 cm)^3 times 1 cm^2/7.92 g times 6.022 times 10^23 atoms/mol times 1/2 atoms E. None of the above

Expert Answer

Answer

length of edge = 2.86 A = 2.86*10^-8 cm

So,

volume of cell = a^3 = ( 2.86*10^-8 cm )^3

mass of unit cell = volume of cell * density

= (2.86*10^-8 cm )^3 * 7.92 g/cm^3

since BCC has 2 atom

mass of 1 atom = mass of unit cell / 2 atoms

= (2.86*10^-8 cm )^3 * 7.92 g/cm^3 * (1/2 atoms)

mass of 1 mol of atoms = mass of 1 atom * 6.022*10^23

mass of 1 mol of atoms = (2.86*10^-8 cm )^3 * 7.92 g/cm^3 * (6.022*10^23 atoms) / 1 mol (1/2 atoms)

This is atomic mass

Answer: A

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